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The Water Framework Directive (WFD) 2000/60/EC, adopted by the European Community in 2000 with the goal of maintaining and improving the aquatic environments, requires that member states achieve and maintain a good ecological status of all water bodies by 2015. In the marine context, the ecological status has to be quantified applying indexes based on appropriate key biological elements, which allow the categorization of water bodies into five Ecological Status (ES) classes. The CARLIT index is a cartographic monitoring tool enabling the Ecological Quality Ratio (EQR) to be calculated using macroalgae in coastal hard bottoms as a key biological element; at present it is being applied in Spain, France and Italy. To detect actual changes of water quality and, consequently, rely on the application of indexes for the assessment of the ecological status in the marine environment, it is necessary to evaluate their sensitivity to natural variability at different temporal and spatial scales. In this study we present a first quantification of natural (spatial and temporal) variability of EQR‐CARLIT quality assessment in 2006 and 2007 along the Ligurian coast (North‐Western Mediterranean, Italy). The EQR‐CARLIT values recorded along the Ligurian coastline show that natural variability of EQR‐CARLIT is low and that it does not affect the attribution of a given stretch of coast to a particular ES class, in agreement with the major human pressures acting in the area (urbanization, river load, sea‐farming). A small‐scale variability was detected, strengthening the use of cartography of the whole rocky shore, whenever possible, or, alternatively, the assessment of the ecological status for long stretches of coast, to encompass the small‐scale variability due to local factors.  相似文献   
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The present paper assesses the use of the supralittoral amphipod Talitrus saltator as a bioindicator of the effects of human trampling on the supralittoral sandy band. Samplings in delimited areas were carried out at sites subjected to different human impact. The results showed a strong negative correlation between the number of swimmers and the sandhopper population density, while there was no clear relationship between sandhopper abundance and the other factors considered: granulometry, compactness and organic carbon content of the sand, and trace metal contents in the sand and sandhoppers. A field test of trampling conducted in a confined space showed its direct negative effect on sandhopper survival. However, trace metal analysis confirmed the ability of T. saltator to bioaccumulate some elements (Hg, Zn, Cu, Cd). Our study demonstrates that T. saltator is a good bioindicator of human impact in the supralittoral zone of sandy shores.  相似文献   
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Water, suspended matter and sediment samples from a system heavily impacted by wastewater from numerous small tanneries (the upper Dunajec River, southern Poland) were collected to establish the annual cycle of Cr. To study possible oxidation processes the speciation of Cr and Mn concentrations were also investigated. This study showed that Cr(III and VI) temporal and spatial distributions are regulated by coupled anthropogenic (source location and emissions) and hydrologic factors (water flow and particle transport). Chromium(III) concentrations in all compartments varied seasonally as a function of the hydrological regime, production cycle in tanneries and distance from the discharge location. Cr(III) was largely associated with the particulate phase and rapidly deposited in river bed sediments. Contaminated river sediments were however flushed during flood periods to the reservoir located downstream from tanneries. During the tanning season (November to March), Chromium(III) concentrations in the water column and total Cr concentration in sediments exceeded relevant ecotoxicological guidelines only upstream from the reservoir, which trapped about 70% of the annual Cr(III) load transported by the Dunajec river. A correlation between Cr(VI)/Cr(III) ratios and Mn concentration in sediments downstream from the reservoir suggests the possibility of Cr(III) oxidation in natural conditions.  相似文献   
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The Piemonte regional warning system service, managed by the Environmental Protection Agency of Piemonte (“ARPA Piemonte” as official Italian acronym), is based on an advanced meteo-hydrological automatic monitoring system, and it is integrated with forecasting activities of severe weather-related natural hazards. At present, a meteo-hydrological chain is operated to provide flood forecasting on the main river pattern. The development of a forecasting tool for shallow landslides triggered by heavy rainfall is presented. Due to the difficulties in modelling shallow landslides triggering in a large and complex area like the Piemonte region, an empirical model is developed on the basis of the correlation between rainfall and previous landslides in historical documents. The research focuses on establishing rainfall thresholds for landslides triggering, differentiating the critical rainfall values through a geological characterisation of the different territories. The period from 1990 to 2002 is considered. A total number of 160 landslides with hourly information and time of triggering are used to calibrate the system. As a first outcome, two different zones have been identified: (1) zones in alpine environments, principally characterised by a bedrock composed of metamorphic rocks, igneous rocks, dolostones or limestones that require high values of critical rainfall and (2) zones in hilly environments, principally characterised by sedimentary bedrock that require low values of critical rainfall. Verification has been performed on a total number of 429 landslides with known date of occurrence. The results show a good agreement with the model with no missed alarms and a very low number of false alarms, thus suggesting an effective operational implementation.  相似文献   
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The use of real-time landslide early warning systems is attracting the attention of the scientific community, since it allows to assess “where” and “when” a shallow rainfall-induced landslide might occur by coupling rainfall amounts, hydrological models and slope-stability analysis. The paper deals with the main results of a back analysis, which refers to the application of a physically based stability model [Shallow Landslides Instability Prediction (SLIP)] on regional scale. The analysis concerns the occurrence of some recent rainfall-induced shallow landslides in the municipal territory of Broni, in the area of Oltrepò Pavese (Northern Italy). The study area is a hilly region 2.4 km2 wide, where more than 40 % of the territory has slopes steeper than 15° and altitudes are between 90 and 250 m a.s.l. As regards the geologic setting, clayey-silty shallow colluvial deposits, with a maximum thickness of about 3 m, overlap a bedrock made of clayey shales, calcareous flysch and marls. The SLIP model is based on the limit equilibrium method applied to an infinite slope and on the Mohr–Coulomb strength criterion for the soil. By assuming that the main hydro-geotechnical process that leads to failure is the saturation of parts of the soil, the model allows to take into account the condition of partial saturation of the soil. The safety factor (F S ) of a slope is also function of previous rainfalls. After the implementation of the model at territory scale, the input data have been introduced through a geographic information systems platform. In the current paper we mainly intend to evaluate the performance of SLIP at catchment scale, by comparison to (1) observed landslide events and (2) another well-established physically based model (TRIGRS). Further, we want to assess the suitability of the model as early warning tool. The results produced by the model are analyzed both in terms of safety factor maps, corresponding to some particular rainfall events, and in terms of the time-varying percentage of unstable areas over a 2-year span period. The paper shows the comparison between observed landslide localizations and model predictions. A quantitative comparison between the SLIP model and TRIGRS is presented, only for the most important event that occurred during the analyzed period. Overall, the results of the stability analyses based on observed rainfalls show the capability of the SLIP model to predict, in real-time and on a wide area, the occurrence of the analyzed phenomena.  相似文献   
17.
Six Cr‐spinel grains from NWA 6077 brachinite‐like and NWA 725 winonaite achondrites have been studied by single‐crystal X‐ray diffraction and structural refinement. From a chemical point of view, spinels from NWA 6077 show Cr/(Cr + Al) (i.e., Cr#) and Mg/(Mg + Fe2+) (i.e., Mg#) values similar to other brachinites, while the Cr# of NWA 725 is lower than that of literature winonaites. Spinels from NWA 6077 and NWA 725 meteorites show similar cell edges, while the oxygen positional parameter is rather different being about 0.2629 for NWA 6077 and 0.2622 for NWA 725. Considering both parameters, NWA 725 shows structural features that are close to some terrestrial spinel occurrences as in komatiites, kimberlites, or included in diamonds; those from NWA 6077 show values that have no terrestrial analogs. Olivine‐chromite closure temperature ranges from ~737 to ~765° C for NWA 725, being similar to that of literature winonaites and ~846 to ~884° C for NWA 6077. The logfO2 ranges from ?19.8 to ?20.5 and ?17.0 to ?17.9 for the two meteorites, respectively. The u values for terrestrial samples can give information about the cooling history of the samples. For the extraterrestrial samples, it seems that it can give information about the cooling only for spinels where it is lower than 0.2625. For higher values, it appears related only to the chemistry of the spinels.  相似文献   
18.
This work presents an algorithm for the scientific analysis of individual calibrated measurements from the Planetary Fourier spectrometer (PFS).The instrument, included in the scientific payload of the ESA Mars Express mission to Mars, acquires spectra in the range between 250 and 8200 cm−1, with a sampling step of ∼1 cm−1 and an effective resolution of ∼2 cm−1. The observed radiance depends on several parameters of the atmosphere and surface of Mars as described by the radiative transfer equation. Adopting the very general formalism of Bayesian analysis, we determined which quantities are actually retrievable from individual measurements. Namely, they are: the surface temperature, the column density of dust and water ice aerosols in the atmosphere, the air temperature as a function of altitude (in the indicative range 5-45 km above the surface), the surface pressure, and the column density of water vapor and carbon monoxide. These evaluations are carried out taking into account the noise equivalent radiance (NER) of the instrument and the natural variabilities of the investigated parameters in the Martian environment, as estimated from the expectations of the European Martian Climate Dataset v3.1 (EMCD). Other parameters included in the radiative transfer equation shall be assumed as known, because they are not retrievable from individual measurements due to the instrumental NER or an underconstrained inverse problem: the surface emissivity in the thermal infrared, the optical properties of suspended dust and the analytical shape of dust concentration vs. altitude.During the development of the algorithm devoted to these studies, different approaches were evaluated on the basis of formal, computational and scientific considerations, with the aim to develop the general design of an integrated software package.The resulting code was extensively tested on a wide set of simulated PFS spectra. These spectra were computed from the atmospheric and surface conditions extracted from the EMCD, assumed to be representative of the Martian environment for different values of latitude, local time and season. Their comparison with the retrievals from simulated observations allowed us to evaluate the systematic and random errors affecting the procedures with respect to the different quantities involved. The code evaluates the surface temperature with an error in the order of 1 K, while the vertical air temperature profile is computed with an uncertainty less than 2 K from in the region between 5 and 20 km above the surface, increasing up to 7 K at 50 km. The column opacity of dust, measured in terms of integrated optical thickness at 1100 cm−1, is computed with an error of around 0.13. The surface pressure determination is carried out with a typical uncertainty of 0.2-0.3 millibar. Several auxiliary tests allowed us to study the correlations between the different retrieval errors and the possible causes of incorrect PFS data interpretation. The choice of a suitable model for the dust optical properties is demonstrated to be particularly critical.This paper also presents the first discussion about application of the procedure to actual PFS Martian data. Despite the calibration issues still affecting the determination of absolute radiance in the near-infrared, the algorithm is able to achieve a satisfactory modeling of observations in a wide range of situations.  相似文献   
19.
For biodiversity research, the field of study that is concerned with the richness of species of our planet, it is of the utmost importance that the location of an animal specimen find is known with high precision. Due to specimens often having been collected over the course of many years, their accompanying geographical data is often ambiguous or may be very imprecise. In this article, we detail an approach that utilizes reasoning and external sources to improve the geographical information of animal finds. Our main contribution is to show that adding external domain knowledge improves the ability to georeference locations over traditional methods that focus solely on analyzing geographical information. Additionally, our system is able to output the confidence it has in its decisions through a confidence measure based on the difficulty of the instance and the steps undertaken to disambiguate it. Our results show that adding domain knowledge to the georeferencing process increases the accuracy @5km from 38.9% to 61.7% and from 47.0% to 74.5% @25km. Furthermore, we reduce the mean distance by more than half, from 251.1km to 114.5km, and decrease the number of records for which no reference can be found from 26.2% to 7.4%.  相似文献   
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